Why? Most Russians are Orthodox, not Catholic
The Vatican has shown a persistent interest in Russia, and yes, there is a significant Russian speaking Catholic minority, as well as a potential convert base. If I remember rightly, Russia (or the USSR) gets a prominent mention in the Fatima narrative.
Russian has declined a lot in importance over the past thirty years, but it is still a major world language in terms of its spread. It is a surprising omission.
The Vatican cannot operate officially within the PRC, but I appreciate the real situation is more complex.