I can't tell you how many times I burned my fingers as a young Unix developer in the 80's by untar'ing things wrongly, or fat-fingering an 'rm -rf /' and thus having a running system that will be catastrophic if I don't fix it before reboot, shell still active and .. what do? Consult this list of great advice and use it to rebuild the system and/or do things that need to be done that otherwise wouldn't be possible ..
GTFOBins is not just for hacking. Its also for system repair and recovery. I'd be as likely to consult this knowledge base after a hacker attack as before, if not more ..
A less typical example is giving a user restricted shell access where they only have access to a few binaries. I think people used to do access control like that in the 90s, but people stopped because its very hard to get right. Its still a very common challenge in CTFs because its very easy to adjust the skill level and come up with new variations.
So they're a pretty niche attack vector, and oftentimes crop up as a result of lazy/incompetent sysadmins.