All three medallists in the women's 800m at the 2016 Rio Olympics were male. This was highly controversial, as having three male athletes take gold, silver and bronze in what should have been a celebration of female athletic excellence wasn't exactly a desirable outcome.
Although the headline of the linked article focuses on males with a transgender identity, the purpose of the IOC's new policy is to exclude all male physiological advantage from the female category, including cases like the above.