Sure, the most common collation scheme for country names is to sort ignoring certain prefixes like "The Republic of", "The", "People's Democratic...", etc. but this is purely a presentation layer issue (how to order a list of countries to a user) that should be independent of your underlying data.
Sure "hacking" the name of the country like this to make the traditional alphabetical ordering match a particular ordering desired to aid human navigation has a lot of history (encyclopedia indexes, library indexes, record stores, etc.) but that was in the age of paper and physical filing systems.
Store the country name correctly and then provide a custom sort or multiple custom sorts where such functionality belongs - in the presentation layer.