It's for online payments only. You click on the wero button on a website/app, if on mobile takes you to your banking app (on desktop, you scan a QR code), you do MFA on your banking app and confirm, and the payment is done.
Wero are not in the business of issuing cards, though obviously they could get into that business - just like UnionPay did in China. I suspect there would be a lot of inertia there, as card payment fees are capped in Europe anyway.