100°F is warm to the touch, not smoking hot. 100°C is boiling hot. You sip tea at 60°C, and brew it at 80° to 100°C depending on the type. You cook chicken to an internal 74°C. A hair dryer blows air around 50°C. All of these are outside of 0-100°F.
> I generally just prefer the Imperial system because of its practicality in everyday life
Funny, most of us much prefer metric mainly for its practicality in everyday life.
Edit: I'll add that aesthetically, 0°C is a really nice zero point for weather. Above 0° is the temperature that the snow starts melting, below is when the streets and ground starts freezing. Which side of 0°C you're on is the biggest pivot point for what it's like outside of any temperature.