Because A0 is defined as having an area of exactly 1 square meter, the paper density (GSM or grams per square meter) maps directly to the weight of the sheet.
>A0 = 1 meter square.
>Standard office paper = 80 gsm
>Therefore, one sheet of A0 = 80 grams.
>Since A4 is 1/16th of an A0, a single sheet of standard A4 paper weighs 5 grams.
I rarely need to use a scale for postage. If I have a standard envelope (~5g) and 3 sheets of paper (15g), I know I'm at 20g total. It turns physical shipping logistics into simple integer arithmetic. The elegance of the metric system is that it makes the properties of materials discoverable through their definitions.