And I really recommend starting with *default* k3s, do not look at any alternatives to cni, csi, networked storage - treat your first cluster as something that can spontaniously fail and don't bother keeping it clean learn as much as you can.
Once you have that, you can use great open-source k8s native controllers which take care of vast majority of requirements when it comes to self-hosting and save more time in the long run than it took to set up and learn these things.
Honerable mentions: k9s, lens(I do not suggest using it in the long-term, but UI is really good as a starting point), rancher webui.
PostgreSQL specifically: https://github.com/cloudnative-pg/cloudnative-pg If you really want networked storage: https://github.com/longhorn/longhorn
I do not recommend ceph unless you are okay with not using shared filesystems as they have a bunch of gotchas or if you want S3 without having to install a dedicated deployment for it.