regarding your question:
I have a 32bit XP version as well, and I actually started with that one.
The problem I was facing was that it's naturally limited to 4GB RAM, out of which only 3.1GB are usable (I wanted to run some beefier models and 64bit does not have the RAM limit).
Also, the 32bit OS kept freezing at random times, which was a very authentic Windows XP experience, now that I think about it. :)