Peltier modules can be used to generate electricity, but they are crazy inefficient.
An efficient steam turbine is largely inaccessible to hobbiests and I am scared of steam/pressure. Though I did look at repurposing a car turbo for this purpose. There were additional issues with regulating the amount of heat you wanted to extract (load matching) and recycling waste heat.
I wondered if it was possible to use a Sterling engine, but you can't buy anything other than very small toys online and I don't have the facilities to machine my own.
Haha, would love to get something working, but I suppose I'm not smart enough to figure out an effective way to get that heat back out as usable/controlled electricity.