My first guess was that the beam of Cf252-emitted neutrons, when it hits the U235, triggers new neutrons moving in the same direction, rather than in random directions. This would ensure that any tertiary neutrons would join the crowd and help the amplification while not just heating the system up.
Or, maybe that's the point? It's a not-quite-critical collection of U235 that is pushed even closer to criticality by the Cf252, multiplying the Cf232's neutron flux by "up to 30 times". But, if the U235 neutrons trigger the same emissions as the Cf252 neutrons, then wouldn't that require a razor's edge of criticality?
https://en.wikipedia.org/wiki/Californium_neutron_flux_multi...