Every game I've tried on Linux was either gold or platinum on ProtonDB and ran fine so far. WINE worked for running a couple non-game apps. Lutris is another way to run programs but I haven't needed it yet.
Definitely try it if you have a machine sitting there. There is so much support for Linux and Mint on the web it was easy to answer any questions I had setting things up.
In the past I migrated to PopOS mainly due to these two things:
1. I prefer flatpaks/system packages over snap[1], if you run `sudo apt install firefox` you'll get a snap application in Ubuntu, that for me is an anti-pattern from Canonical to force adoption of snaps.
2. I found some weird performance issues with my laptop when I installed Ubuntu, thankfully I managed to find a fix after hours of tinkering[2], but I was surprised I had to do these workarounds in the first place (I've been running linux as my main OS since I was a teenager and never had to do anything similar)
If gaming is your main goal I'd consider using something like Bazzite or CachyOS, these two distros will still serve you if you want to run work/office apps too, they just come preconfigured w/ a lot of gaming goodies (like steam and nvidia drivers oob) but won't get into your way if you plan to install other stuff.
[1] https://snapcraft.io/ [2] https://bugs.launchpad.net/ubuntu/+source/linux/+bug/1973434...