Specifically, if you know that one is a girl, then the unordered options seem like they are back on equal footing? That is, it isn't twice as likely if you know that one ordering can't happen? (Or, stated differently, you don't know which version of two girls you are looking at.)
So, for this one, you know that either the youngest is a girl (so, girl-boy is not possible) or that the oldest is a girl (so boy-girl is out). That puts you back to the rest of the possibilities. Boy-boy is out, sure, as you have a girl. But every other path remains? So, you have one of (boy-girl(known), girl-girl(known), girl(known)-boy, girl(known)-girl). Which drops you back to 50/50?