The first is SECURITY BARRIER and LEAKPROOF which gives us an ability to rethink how to multi-tenant applications. This is a game changer and will get even better in future versions I am sure.
The second is NO INHERIT constraints, which I will certainly be making good use of. It is also a complete game changer when it comes to table inheritance and partitioning, and my main use will be things like CHECK (false) NOINHERIT to ensure that a table in fact never has rows of its own.
There is an amazing amount of good stuff going on around Postgres right now. Postgres-XC was recently released, and more. It is an amazing data modelling platform and ORDBMS.