WTF-8 has some inconvenient properties. Concatenating two strings requires special handling. Rust's opaque types can patch over this but I bet Go's WTF-8 handling exposes some unintuitive behavior.
There is a desire to add a normal string API to OsStr but the details aren't settled. For example: should it be possible to split an OsStr on an OsStr needle? This can be implemented but it'd require switching to OMG-WTF-8 (https://rust-lang.github.io/rfcs/2295-os-str-pattern.html), an encoding with even more special cases. (I've thrown my own hat into this ring with OsStr::slice_encoded_bytes().)
The current state is pretty sad yeah. If you're OK with losing portability you can use the OsStrExt extension traits.