Assuming I understand such a feat even with exposure to pure O2, how does he manage to avoid CO2 build-up? Or, how did he train to retain CO2?
Cells use up O2 and release CO2 into the blood to form carbonic acid (keeping it simple), so the blood pH levels drop, which the body does not care about at all. This is what induces the suffocation reflex.
I wish I had known this while trying to master breathing while swimming freestyle: it is not just their VO2 max, but also their ability to retain CO2. Both aspects need to be trained.