There used to be someone who had the email address john@dk (maybe it wasnt john). Mx records on tlds are frowned upon but not technically invalid.
Edit: sorry for the echo, bigiain - I saw your post right after adding the comment.
;; ANSWER SECTION:
ai. 14400 IN MX 10 mail.offshore.ai.
;; ADDITIONAL SECTION:
mail.offshore.ai. 14400 IN A 209.59.119.34I'm unaware of any common MTA software which wouldn't handle it.
I have a cow-orker who's first name is "G" - he's very used to poorly-validating websites claiming that his firstname is "wrong".
I've got another friend/acquaintance who's got a fully legal (self chosen) single name. No first/middle/last name, just a "mononym". He has the expected hilarious outcomes with things like Google's "real name policy".