Many people argue that supply and demand don't apply to the labour market!
Often because they're not even aware of the concept. The more sophisticated claim that it doesn't apply to the labor market.
The minimum wage discussions are dominated by this view.
The supply/demand analysis is simple: If a worker has skills worth $12/hour on the labor market, and the minimum wage is $15, that worker will be unemployed, making 0$/hour. They'll also not learn new skills, since they can't get a job.
Try bringing that up in a minimum wage discussion, and you'll be called many nasty names. Often equalling market wage to human worth, which means you think the poor are lesser humans. A few sophisticates will bring up vague externalities arguments, as if they negate the whole supply/demand concept.
From my perspective minimum wage laws is one of the main factors keeping people in poverty, but that concept is impossible to even explain to most people.
My main thought about externalities is that they their effect is usually minor, and can be ignored. Many of them are also positive. For the bigger ones, it's a case by case analysis.
Is the externality you're thinking of something around the government paying money to the working poor?