It can, but nobody would do that as it would be cheaper to use a DB-25 connector and not use all the pins. If they went for the cursed true DB-9 they would need to meet the minimum order quantity for a special order, pay for the manufacturer's tooling, and any required certifications. If you needed the spacing between pins for some reason you would probably just specify the use of crimp-and-insert.
That being said, the DE-0 is real, but it can't hurt you.