Boarding at the very beginning makes a huge difference.
It's a 30 minute chunk of time in which you get to relax. Once you're in your seat there really is nothing else to do. You can work, you can watch a movie, you can think, read a book.
No latent anxiety wondering when I should get up, no "I can't really focus on this book because I might have to get up any minute," etc.
For a relatively short flight (2 hours) it's a pretty meaningful % of time that becomes a lot more relaxing.