I don't work at Google anymore and don't have any special insight into the internal adoption of io_uring, but I think it stands to reason that Google would benefit tremendously from rolling out a higher-performing way to do IO across their fleet. I mean, having myself done some lowish-level performance/optimization work and knowing that the impact of these kinds of changes is measurable and the scale is almost fleetwide, I wouldn't be surprised if the benefits - after major internal libraries/tools are also updated to use io_uring - are O(Really Big Money)
Having talked to members of their prodkernel team about other subjects, I also think they are competent enough to know the difference between "not ready" and "acceptably flawed". And believe me, the incentives are such that O(Really Big Money) optimization projects get staffed unless there is something making them infeasible.
Not everybody has the same threat model and security stance as Google and that's ok. But personally I would take their internal adoption of io_uring very seriously as a measure of whether it's safe for me to adopt it, especially if I'm running untrusted or third party software (including certain kinds of libraries).