Simple - there is no real lasting money in psylocibin as most people really only need 2 or 3 good sessions.
Whereas adderall is not technically addictive, but if you can function on it, you do become dependent on it.
You also really don't need it to become a prescription, shrooms just need to get legalized. The risks that come from overuse are far and few in between to the point where normal over the counter meds carry much more danger in abuse than shrooms do.