There are places for clever hand code, even in C, even in the modern world. Data interchange is very not much not one of them. Just don't do this. If you want .ini, use toml. Use JSON if you don't. Even YAML is OK. Those with a penchant for pain like XML. And if you have convinced yourself your format must be binary (you're wrong, it doesn't), protobufs are there for you.
But absolutely, positively, never write a parser unless your job title is "programming language author". Use a library for this, even if you don't use libraries for anything else.
[1] Fine fine, lexer. We are nitpicking, after all.