Extremely risky tbh I would have an extremely hard time if I go off path or need to hire someone. It would be almost negligence to choose it unfortunately
If you need to hire someone you'd need to train them on your system no matter what, with a framework you can use their documentation to explain where things are and how they work.
Ash does look badass though!
Elixir and Ruby really aren't that similar anyway. The syntax differences are very superficial - Elixir's a functional language with very style and semantics to Ruby, and that's even before you get into the magic of OTP and the BEAM, for which Ruby has nothing comparable.