You know something that almost never has rounded corners? Glass.
Just kidding: Yeah, it's just that when I think about a digital glass effect it feels more right with square corners than rounded corners. Because glass windows which we look through usually have square corners. Says I, who spend most of my time looking through a curved motorcycle helmet visor.
That's why we have round glass coasters, round lenses, round glasses for drinking, etc.
I'm very curious which items you went through before concluding that glass almost never has rounded corners.