ZFS was not leveraged that much but it saved our beacon once when a table in the production database was accidentally dropped and we could instantly rollback to the previous zfs snapshot (there was a tiny bit of data loss as a result but this did not matter too much for this application - uptime was more important). ZFS was also used for backups I believe.
A few times I used dtrace in production to troubleshoot.
When we introduced Linux to our fleet of FreeBSD servers, every team picked a different distro organically so it was a bit of a zoo. With FreeBSD on the server you only have the one variant.
I still use and like both, but I must say I really like that FreeBSD is a kernel+OS integrated together.