What will you have achieved after you "hammer" them on that technology?
Will you genuinely be closer to assessing whether that candidate can do the job you need done?
I think that it is reasonable to ask questions about what is on a resume.
I told them I had been coding in C++ for four years.
They said "So what level are you, Expert or Guru?"
I thought it was a trick question, and replied that anyone who calls themselves an "expert" after less than 7 years or "guru" after less than 12, is probably over-representing their skill level.
Unfortunately (1) they were serious, (2) what I said applied to all three of my interviewers and (3) it was an internal interview. I had to leave the company very soon afterward. My former boss insisted that I was at least as skilled (at coding) as those three (I passed the technical questions comfortably), and it was just my reluctance to self-promote that let me down.
I don't regret it at all. I would not have done well in that culture, whether I had the coding skills or not. And I avoided having to move (1000s of miles.)
A better rule is to put a language on your resume when you can think of a question, and you immediately know how to approach (not solve) the problem using language X.