The counterargument is that morning needs light more than evening because morning schedules are more synchronized than evening schedules and morning road conditions tend to be worse than evening road conditions.
So in the morning you've got the highest concentration of cars plus you've got kids walking or biking to school.
The school day is shorter than the work day so coming home the kids don't overlap with the workers. There is more time variation in when people leave work when they arrive, and many will do errands between living and driving home, so the cars are less concentrated.
Morning also has a higher chance of having worse road conditions. In the evening there is a chance the sun has melted ice patches that formed overnight. There's a chance that the day's traffic has cleared some paths in snow.