When you don't have any adrenal stimulants in your diet at all, even a small amount is noticable.
Caffeine also has a metabolic half life of roughly 5 hours in the body, if I remember correctly. A few berries might not do much, but surely a handful will be enough.
If you want a jolt, make a matcha shot with the same mass of matcha as you would normally do for coffee ;)
For staying productive for hours, nothing beats Maté for me (except stimulant medication).
Here is an article that further describes how we believe caffeine synthesis evolved in multiple land plant lineages.
https://www.pnas.org/content/113/38/10613
Caffeine synthesis involves several enzymes, but the enzyme family (called the SABATH family) involved in the final stages of its synthesis can trace its origins back to the first land plants. These first enzymes are thought to have been very promiscuous (capable of having activity with several molecules), partially contributing to how caffeine synthesis managed to evolve independently multiple times throughout the evolutionary history of land plants.
Kinda like ok you can eat a poppy but then there’s a reason morphine exists. (Sorry for the stupid analogy ;)
I think the causality went the other way in that case. I've been roughly caffeine free at certain intervals. Never felt anything from chocolate.
I say "almost" caffeine free because I still regularly ate chocolate. So I still had a little tolerance. Yet the difference between 50g of milk chocolate and 300g of 90% was very noticeable.
I find it hard to believe that some folks would feel the caffeine in chocolate unless they ate an entire dark chocolate bar in one sitting, but I suppose it's possible.
For that matter 24oz is rather a lot of coffee to drink at once. I brew my daily coffee with 200g of water, or only about 7 floz.
So; with that said, while I believe that eating 28oz of chocolate is a lot, I guess it could happen :-)
But anyway, I've been to a coffee shop or two, and I've never seen a "standard cup" as anything other than 12 ounces.
That's not just an outlier, that's absurd. At 100mg caffeine per 8oz of coffee, that's over 6 grams of coffee per day, or more than 15 times the amount generally considered safe.
(3 pots of coffee) is about (180 oz).
I’m never making that mistake again and I’m making up for lost time.
Ghiradelli claims their dark chocolate has 20mg per oz and their milk chocolate has 6 mg per ounce. [1]
That would mean eating a standard 3.5oz/100g chocolate bar would have 70mg of caffeine for dark, or 21mg for milk.
While 3.5oz is a lot in a sitting, 70mg is equivalent to a smallish cup of coffee.
[1] https://www.ghirardelli.com/product-faqs#:~:text=Dark%20choc...
Maybe for a subset of people. Otherwise kids will be getting crazy jitters the first time they eat chocolate (presumably before they ever drank coffee/tea), which obviously doesn't happen.
If you're paying attention to your body and you're not addicted to stimulants, then a small kick of caffeine would absolutely be noticeable.