There are plenty of things that look simpler than an established library at first glance (I/O of specialized formats comes to mind quickly). However, a lot of the complexity of that established library can wind up being edge cases that you actually _do_ care about, you just don't realize it yet.
It's easy to wind up blind to maintenance burden of "just a quick add to the in-house version" repeated over and over again until you wind up with something that has all of the complexities of the widely used library you were trying to avoid.
With that said, I still agree that it's good to write things from scratch and avoid complex dependencies where possible! I just think choosing the right cases to do so can be a bit of an art. It's a good one to hone.