The wikipedia page for LIPs notes the correlation in time between LIPs and mass extinctions: 'The formation of LIPs is variously attributed to mantle plumes or to processes associated with divergent plate tectonics. The formation of some of the LIPs in the past 500 million years coincide in time with mass extinctions and rapid climatic changes, which has led to numerous hypotheses about causal relationships.’
However, those might not be the Devonian and Ordovician extinction events referred to in this article. Do we know if any LIPs formed at the time of those two events?