NSCountedSet - and NSMutableSet that keeps counts of objects added
NSValueTransformer - More of a design pattern for generically converting objects
NSArgumentDomain in NSUserDefaults - command line arguments of -key value become user defaults
NSXMLNode nodesForXPath:error:/objectsForXQuery:error: - run XPath or XQuery against XML... even better, subclass NSXMLNode and then use XPath and XQuery on any hierarchical data you have
NSObject's performSelectorOnMainThread:withObject:waitUntilDone: - use NO for waitUntilDone and the method will be called at the end of the event loop (I've seen many people use the afterDelay variant instead)
NSNotificationQueue - use NSNotificationCoalescingOnName to batch up NSNotifications to send a single one at the end of the event loop, though there's lots of gotchyas for using it correctly
NSOrthography - Okay, even I didn't know about this before re-glancing at the foundation reference :)