Personally I don't trust a NAS as far as I can throw it, or rather I'd use one the way I use Amazon S3.
My home server has a ZFS array, the media server and some other programs access it directly. If I want to move files to or from it I use SFTP. If I want to back files up to it I use rsync. I have Lightroom running pretty good on an external HDD, no way I'd take my chances running it on a NAS.