Neither Albany, NY not Sacramento, CA feel like the centers of their states.
Adding a few more examples to your list, neither Olympia (WA), Salem (OR), nor Carson City (NV) are economic or social centers of their respective states.
Sacramento may not be exciting, but it is self-sustaining with fairly high property costs and a huge commuter population. I think one of the things that makes California successful is the government is in a boring city with few distractions.