I live here 15 years and cross borders to France and Austria quite often. Of course not 100% of the checkpoints are manned 100% of the time, I know quite a few small ones around Geneva for example where you could smuggle truckload of heroin 24/7 for a decade without any worry of ever seeing border police. Also checks are random and not focused on specific things, sometimes romanian van chock full of stuff is stopped and sometimes its swiss family car.
But all major are and were in the past, all frontaliers coming daily for the jobs in all border cantons can tell you about wonders of morning checks corresponding massive traffic jams forming in front of the border crossings, every single day. 1/3 of my office colleagues experience this every day.
Major eastern border crossings are 100% manned though, morning day night doesn't matter.