Sure, I get a little anxious when people misuse your/you're. But to think it's an early indicator of success is at best limiting yourself to missing out on talent, and at worse surrounding yourself with likeminded pedantic grammar nazis who care about unimportant things. In my time as a software developer, I've met a lot of people who got angsty about grammar who weren't very inspiring programmers. I've met more people who couldn't figure out their and there or you're and your to save their lives who were both fantastically good software engineers and effective communicators.
Lets keep a little perspective here: The goal of hiring isn't to find someone who's not going to annoy you by misusing grammar in emails. It's to find someone who's going to help you accomplish your goals. I get that details are important for your company. I just don't agree that knowing grammar rules indicates an attention to the proper details.