There is no "rail network" about which the US (through some political process) makes decisions about prioritization.
There is a freight rail network, and there is Amtrak's rails between Boston and DC. That's it. We're not prioritizing freight, the network is owned by freight companies.
Also, with regards to percentages, this is the wrong comparison. The numbers you need (which I could not find) are what percentage of cargo travels to within Nkm of its destination by trail in the USA, where N is the typical value for Europe. We have substantial freight hauling in the US because of long distance journeys. The last Nkm is generally done by truck. In Europe, there is much less long distance freight hauling, and much more hauling that takes place under the Nkm "limit", ergo more is done by truck.