Can you tell us what exactly do you solder at 320ºC and what is the exact type of solder you use and/or Pb and Sn percentages?
Also, is your pinecil calibrated? And which tips do you use at that temperature?
Anecdotally, what usually happens to me at lower temps is the tip and/or the solder wire sticking a bit while I'm soldering which I take as a sign that the liquid solder won't flow correctly and that I have to spend more time giving it heat from tip, than I should.
I only bump it up to 400 C because that was the default, I never use it for more than two or three seconds so the temperature hasn't mattered much. I haven't noticed solder stick, it just sometimes fail to melt properly with large ground planes, so that's when I bump the heat.