Non-native here.
These composed verbs, whose meaning depend on the modifiers, are definitely confusing.
You can go a long way without mastering them, and their meaning (assuming there's only one) isn't always easy to infer from the roots. Think of getting off, for example.
Some of the combinations are still not part of my passive vocabulary[1], and most are not part of my active vocabulary, because I can usually get away with synonyms.
For this scenario, "log in" and "register" offer the best syntactic contrast, and should be favored, IMO. "Sign in" and "sign up" require more thinking. Pet peeve of mine, actually.
[1] There was a vocabulary depth study posted here on HN a while ago, I was at the 95th percentile of non-native speakers, equivalent to the median of natives of my age.