All of the following are "for now, as you start out":
Do not gyrate over which version of HA to run. Run the HAOS loaded on RasPi, or a dedicated machine. You can migrate to other solution if that does not end up to be the best choice.
Make sure you get the latest Zigbee radio dongle the HA Forum recommends. I use in all my HA installs a combination dongle for Zigbee & Z-Wave and it works flawlessly (NORTEK Quickstick Combo).
Start with a few cheap Zigbee devices. Stay away from WiFi, LoRaWAN and other solutions. Z-Wave devices are great, but more expensive. You know you do not know if you even want to do this.
Initially, just use the built-in Zigbee (ZHA) integrations. Once you are comfortable deploying other ways, like MQTT can be established easily.
Do not spend too much on the devices now. I suggest you pick up a PIR motion sensors, door & window opening sensors, temperature & humidity sensors, smart plugs, and light bulbs. Anything else is overkill to try out. Sub-tip: all of these are battery operated, so try to consolidate on a standard battery. The ones I listed can all run off of 2032 cell batteries. Ikea sells most of these, Aqara is well known, and so on. If it is Zigbee (not Matter) you will have 96% chance it will work with HA.
Have fun!