It seems we need diffrent categories for a ranking: premises vs. base area of the buildings vs. floor area of the buildings vs. largest building per base area vs. largest building per floor area, etc. And then we would need to clarify what counts in each case ...
Anyway, I live about 20 km from BASF and it is quite an impressive sight, especially at night. Here is a photo: https://de.m.wikipedia.org/wiki/Datei:Fackelschein_des_Steam... However, the red lights are probably an artefact of the camera; typically the lights looks rather bluesh in reality. And the photo was shot with a 400 mm lens: the television tower in the foreground is more than 4 km away from the factory, the house at the left about 3 km.
Anyway, cool that Germany still has the biggest of something ~heavy industry.
[1] https://twitter.com/TaylorOgan/status/1859149340897628545
https://en.wikipedia.org/wiki/Dallas_Fort_Worth_Internationa....
While that is a ton of activity (and empty space, if you have ever seen those airports), the Big Apple might not be the best reference for scale.