Astra at Sandia Labs was the first Arm peta-scale supercomputer, and the first on the Top500. It debuted in 2018.
Fugaku is the fastest Arm supercomputer, taking the #1 spot on the Top500 in 2020. It is currently #4.
All NVIDIA Grace-Hopper systems will be Arm. There is one in the top 10 already, Alps at the Swiss CSCS, at #6. There are four more in the top 100.