If you're using Google for identity and authentication, you can definitely control who has an active account in your domain. There can be some lag time before disabling or removing someone truly disables all their downstream accesses, but that's largely outside Google's control. The only way to trick your way into getting a corporate domain email address is to socially engineer a domain admin.
Tangentially, this does raise one of my big issues with using OAuth2 for single-sign-on though, which is that it really doesn't address the third-party authorization problem well. Ok, you're bob@example.com, Google has verified that, and example.com is our domain, so we're letting you into our app Foobar. Now what? The scopes you requested were for Google APIs only and have nothing to do with Foobar really. So now we need to implement an authorization system in Foobar that decides what bob@example.com can actually do. This part, and how to do it right, gets glossed over (at best!) by discussions on OAuth2. It also gets glossed over by product and security when they want things "SSO-enabled", which means development time doesn't get budgeted for it. Even just using groups to control coarse access levels requires integration with provider-specific APIs. OAuth2 is great for identity and authentication, but far too little attention has been paid to doing authorization right.