I don't quite understand it, but apparently anything which can be used to distinguish the children will do.
Possibilities with two children:
Gg, Bg, Gb, Bb
If one of them has a distinguishing mark, they have an apostrophe: (in jail, has red hair, or born first) G'g, B'g, G'b, B'b, Gg', Bg', Gb', Bb'
Then note that the marked one is a girl: G'g, G'b, Gg', Bg'
So, there is a 50% change that the children are a boy and a girl. Only if there is no way to distinguish them, do you get the 66% behaviour, where the set is: Gg, Bg, Gb