Rich's observation was that query optimizers often get things wrong in ways that are hard to predict or control, but he's not fundamentally opposed to their use. That said, building a decent optimizer is a huge undertaking and I think they took the right decision to not attempt to bundle that sort of complexity into the original vision for Datomic otherwise they might never have shipped.
The state-of-the-art commercial engine for query optimization and execution algorithms in this 'triple' space is probably https://relational.ai/