A key part of a lot of these pygtk players is that they rely on gstreamer to do the heavy lifting. Organizing a pipeline of "this source, this format, that sink" is not a performance problem -- it's a plumbing task. :)
I understand Python could be a good choice and, yes, I agree it would be "easier". But jeez you know.. I just want to use C damn it. I want complete control over the memory. WHY CAN'T I JUST USE C?!! haha