That's kind of how we got LSD, saccharin and microwave ovens. (not really "playing with" but not being super careful about safety)
Even when the play is "touching" and the chemicals are "food dyes"? I wouldn't say I'm a risk taker, but even I would probably try that out for giggles.
Even if not intentional, such things happen by accident. Have you ever read up on how the psychedelic properties of LSD were discovered?
> While re-synthesizing LSD, he accidentally absorbed a small amount of the drug and discovered its powerful effects