When SPDY, the precursor of HTTP/2, got introduced, it needed a mechanism to signal that within TLS, a different protocol (SPDY instead of HTTP/1.1) was spoken. That mechanism was originally NPN. I don't know the exact details and motivation, but eventually people seem to have decided that NPN wasn't exactly what they wanted, and they invented a new mechanism called ALPN.
Now, that was a decade ago (the ALPN RFC is from 2014), so the question is: why do we still have NPN code in OpenSSL? I don't think anyone uses it any more. Shouldn't it have been removed long ago?
To put this in a larger context: it appears to me that OpenSSL still has a strong tendency to bloat. Heartbleed was essentially a "we added this feature, although noone knows why we need it" kind of bug, but it doesn't look to me they've changed. I still get the feeling that OpenSSL adds many features that they probably just should ignore (e.g. obscure "not invented here"-type algorithms), and they don't remove features that are obsolete.