Actually executables you can reverse engineer it into something that could be compiled back into an executable with the exact same functionality, which is AFAIK impossible to do with "open weights". Still, we don't call free executables "open source".
And yes, like other executables, they are not literal black boxes. Rather, they provide machine readable specifications which are not human readable without immense effort.
For an LLM to be open source there would need to be source code. Source code, btw, is not just a procedure that can be handed to a machine to produce code that can be executed by the machine. That means the training data and code is not sufficient (or necessary) for an open source model.
What we need for an open source model is a human readable specification of the model's functionality and data structures which allows the user to modify specific arbitrary functionally/structure, and can be used to produce an executable (the model weights).
We simply need much stronger interpretability for that to be possible.